trans-Bis(benzyldiphenylphosphane-κP)dichloridoplatinum(II)
نویسنده
چکیده
In the mononuclear title compound, trans-[PtCl2(C19H17P)2], the slightly distorted square-planar coordination sphere of the Pt(II) atom is occupied by two benzyl-diphenyl-phosphane ligands and two chloride atoms in a mutually trans geometry. The effective cone angles for the two phosphane ligands are 160 and 169°. C-H⋯Cl inter-actions generate infinite long chains along [01-1]. Additional C-H⋯π and π-π stacking interactions [centroid-centroid distance = 4.2499 (15) Å and ring slippage = 2.386 Å] are observed.
منابع مشابه
cis-Bis(benzyldiphenylphosphane-κP)dichloridoplatinum(II) dichloromethane sesquisolvate
The asymmetric unit of the title compound, [PtCl(2)(C(19)H(17)P)(2)](2)·3CH(2)Cl(2), contains two complex mol-ecules and three dichloro-methane solvent mol-ecules, two of which are disordered over various positions. The Pt(II) complexes reveal a slightly distorted square-planar geometry with average Pt-P and Pt-Cl bond lengthss of 2.252 (8) and 2.363 (8) Å, respectively, and average P-Pt-P and ...
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